Superlattice Design Realizes Elusive Multiferroic Properties

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From the spinning disc of a computer’s hard drive to varying current in a transformer, many technological devices work by merging electricity and magnetism. Enter multiferroics, which combine 2 or more primary ferroic properties. Northwestern University’s James Rondinelli and his research team are interested in combining ferromagnetism and ferroelectricity, which rarely coexist in one material at room temperature.

In order for ferroelectricity to exist, the material must be insulating. So nearly every approach to date has focused on searching for multiferroics in insulating magnetic oxides. Rondinelli’s team started with a different approach. They instead used quantum mechanical calculations to study a metallic oxide, lithium osmate, with a structural disposition to ferroelectricity and sandwiched it between an insulating material, lithium niobate.

While lithium osmate is a non-magnetic and non-insulating metal, lithium niobate is insulating and ferroelectric but also non-magnetic. By alternating the 2 materials, Rondinelli created a superlattice that—at the quantum scale—became insulating, ferromagnetic, and ferroelectric at room temperature.

Illustration of the polar zone-center mode along the [101]-direction labeled by irrep Γ−2. Antipolar displacements along the [010] direction are omitted for clarity.

Illustration of the polar zone-center mode along the [101]-direction labeled by irrep Γ−2. Antipolar displacements along the [010] direction are omitted for clarity. Credit; http://journals.aps.org/prl/abstract/10.1103/PhysRevLett.115.087202

“The polar metal became insulating through an electronic phase transition,” Rondinelli explained. “Owing to the physics of the enhanced electron-electron interactions in the superlattice, the electronic transition induces an ordered magnetic state.”

APPS: This new design for multiferroics could open up new possibilities for electronics, including logic processing and new types of memory storage. Multiferroic materials also hold potential for low-power electronics as they offer the possibility to control magnetic polarizations with an electric field, which consumes much less energy.
“Our work has turned the paradigm upside down,” Rondinelli said. “We show that you can start with metallic oxides to make multiferroics.” http://www.mccormick.northwestern.edu/news/articles/2015/08/superlattice-design-realizes-elusive-multiferroic-properties.html

a) The superlattice exhibits the a−b−b− tilt pattern. Atom- and orbital-resolved DOS for (b) LiOsO3, (c) LiNbO3 and (d) LiOsO3/LiNbO3 at the DFT-LDA level. EF is given by the (broken) vertical line at 0 eV.

(a) The superlattice exhibits the a−b−b− tilt pattern. Atom- and orbital-resolved DOS for (b) LiOsO3, (c) LiNbO3 and (d) LiOsO3/LiNbO3 at the DFT-LDA level. EF is given by the (broken) vertical line at 0 eV. Credit: http://journals.aps.org/prl/abstract/10.1103/PhysRevLett.115.087202