Batteries that “Drink” Seawater could power Long-Range Underwater Vehicles

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Open Water Power’s battery that "drinks" in sea water to operate is safer and cheaper, and provides a tenfold increase in range, over traditional lithium-ion batteries used for unpiloted underwater vehicles. The power system consists of an alloyed aluminum anode, an alloyed cathode, and an alkaline electrolyte positioned between the electrodes. Components are only activated when flooded with water. Once the aluminum anode corrodes, it can be replaced at low cost. Credit: Open Water Power

Open Water Power’s battery that “drinks” in sea water to operate is safer and cheaper, and provides a tenfold increase in range, over traditional lithium-ion batteries used for unpiloted underwater vehicles. The power system consists of an alloyed aluminum anode, an alloyed cathode, and an alkaline electrolyte positioned between the electrodes. Components are only activated when flooded with water. Once the aluminum anode corrodes, it can be replaced at low cost. Credit: Open Water Power

The long range of airborne drones helps them perform critical tasks in the skies. Now MIT spinout Open Water Power (OWP) aims to greatly improve the range of unpiloted underwater vehicles (UUVs), helping them better perform in a range of applications under the sea. Recently acquired by major tech firm L3 Technologies, OWP has developed a novel aluminum-water power system that’s safer and more durable, and that gives UUVs a 10X increase in range over traditional lithium-ion batteries used for the same applications.

The power systems could find a wide range of uses, including helping UUVs dive deeper, for longer periods of time, into the ocean’s abyss to explore ship wreckages, map the ocean floor, and conduct research. They could also be used for long-range oil prospecting out at sea and various military applications. With the acquisition, OWP now aims to ramp up development of its power systems, not just for UUVs, but also for various ocean-floor monitoring systems, sonar buoy systems, and other marine-research devices.

OWP is currently working with the US Navy to replace batteries in acoustic sensors designed to detect enemy submarines. This summer, the startup will launch a pilot with Riptide Autonomous Solutions, which will use the UUVs for underwater surveys. Currently, Riptide’s UUVs travel roughly 100 nautical miles in one go, but the company hopes OWP can increase that distance to 1,000 nautical miles. “Everything people want to do underwater should get a lot easier,” says co-inventor Ian Salmon McKay ’12, SM ’13, who co-founded OWP with fellow mechanical engineering graduate Thomas Milnes PhD ’13.

Most UUVs use Li-based batteries, which have several issues. They’re known to catch fire, for one thing, so UUV-sized batteries are generally not shippable by air. Also, their energy density is limited, meaning expensive service ships chaperone UUVs to sea, recharging the batteries as necessary. And the batteries need to be encased in expensive metal pressure vessels. In short, they’re rather short-lived and unsafe. In contrast, OWP’s power system is safer, cheaper, and longer-lasting. It consists of a alloyed aluminum, a cathode alloyed with a combination of elements (primarily nickel), and an alkaline electrolyte that’s positioned between the electrodes.

When a UUV equipped with the power system is placed in the ocean, sea water is pulled into the battery, and is split at the cathode into hydroxide anions and hydrogen gas. The hydroxide anions interact with the aluminum anode, creating Al(OH)3 and releasing electrons. Those electrons travel back toward the cathode, donating energy to a circuit along the way to begin the cycle anew. Both the aluminum hydroxide and hydrogen gas are jettisoned as harmless waste. Components are only activated when flooded with water. Once the aluminum anode corrodes, it can be replaced at low cost.

Think of the power system as type of underwater engine, where water is the oxidizer feeding the chemical reactions, instead of the air used by car engines, McKay says. “Our power system can drink sea water and discard waste products,” he says. “But that exhaust is not harmful, compared to exhaust of terrestrial engines.”

With the aluminum-based power system, UUVs can launch from shore and don’t need service ships, opening up new opportunities and dropping costs. With oil prospecting, for example, UUVs currently used to explore the Gulf of Mexico need to hug the shores, covering only a few pipeline assets. OWP-powered UUVs could cover hundreds of miles and return before needing a new power system, covering all available pipeline assets. Consider also the Malaysian Airlines crash in 2014, where UUVs were recruited to search areas that were infeasible for equipment on the other vessels, McKay says. “In looking for the debris, a sizeable amount of the power budget for missions like that is used descending to depth and ascending back to the surface, so their working time on the sea floor is very limited,” he says. “Our power system will improve on that.” http://news.mit.edu/2017/batteries-drink-seawater-long-range-autonomous-underwater-vehicles-0615