Electron microscope images of visible-NIR light responsible photocatalyst composed with black phosphorous (BP), lanthanum titanate (LA2Ti2O7, LTO), and gold nanoparticles (Au).
Credit: © Zhu M, Cai X, Fujitsuka M, Zhang J, Majima T, Angewandte Chemie: International Edition 56 (2017)
Osaka University researchers create new material based on gold and black phosphorus to produce clean hydrogen fuel using the full spectrum of sunlight. Hydrogen can be generated by splitting H2O, but this uses more energy than the produced hydrogen can give back. Water splitting is often driven by solar power, so-called “solar-to-hydrogen” conversion. Materials like titanium oxide, known as semiconductors with the wide band-gap, are traditionally used to convert sunlight to chemical energy for the photocatalytic reaction. However, these materials are inefficient because only the ultraviolet (UV) part of light is absorbed – the rest spectrum of sunlight is wasted.
Now, a team in Osaka University has developed a material to harvest a broader spectrum of sunlight. The three-part composites of this material maximize both absorbing light and its efficiency for water splitting. The core is a traditional semiconductor, lanthanum titanium oxide (LTO). The LTO surface is partly coated with Au nanoparticles. Finally, the gold-covered LTO is mixed with ultrathin sheets of the element black phosphorus (BP), which acts as a light absorber.
“BP is a wonderful material for solar applications, because we can tune the frequency of light just by varying its thickness, from ultrathin to bulk,” the team leader Tetsuro Majima says. “This allows our new material to absorb visible and even near infrared light, which we could never achieve with LTO alone.” By absorbing this broad sweep of energy, BP is stimulated to release electrons, which are then conducted to the gold nanoparticles coating the LTO. Gold nanoparticles also absorb visible light, causing some of its own electrons to be jolted out. The free electrons in both BP and gold nanoparticles are then transferred into the LTO semiconductor, where they act as an electric current for water splitting.
Hydrogen production using this material is enhanced not only by the broader spectrum of light absorption, but by the more efficient electron conduction, caused by the unique interface between two dimensional materials of BP and LTO. As a result, the material is 60X more active than pure LTO. “By efficiently harvesting solar energy to generate clean fuel, this material could help to clean up the environment,” Majima says. “Moreover, we hope our study of the mechanism will spur new advances in photocatalyst technology.”
http://resou.osaka-u.ac.jp/en/research/2017/20170529_1
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