A slice of (white) lithium garnet electrolyte coated with a (black) lithium compound acting as the battery’s minus pole in the laboratory of the ETH researchers. Credit: ETH Zurich / Fabio Bergamin
A new lithium-ion battery made entirely of solid material has been developed by scientists. It has neither liquids nor gels. The battery is non-flammable, even at very high temperatures, giving it a safety advantage over conventional batteries. Mobile phones, laptops, e-bikes and electric cars are all powered by such batteries.
Conventional lithium-ion batteries are not without their dangers: mobile phone batteries have exploded several times in the past, resulting in injuries, and only 6 months ago an entire row of houses burned down in the old town of Steckborn on Lake Constance. The blaze was caused by a model-making battery that allegedly caught fire due to being charged improperly.
In conventional lithium-ion batteries as well in most other batteries, the 2 electrodes are made of solid conductive compounds; charges move between these electrodes in a liquid or gel electrolyte. If you charge such a battery improperly (overcharging) or leave it sitting out in the sun, the liquid can ignite or the gel can swell up. This is not the case with solid-state batteries.
(Scheme: Van den Broek J et al., Advanced Energy Materials 2016, adapted)
One of the challenges in developing solid-state batteries is to connect the electrodes and electrolyte in such a way that the charges can circulate between them with as little resistance as possible. The ETH researchers have now developed an improved electrode-electrolyte interface. In the laboratory, they constructed a sandwich-like battery featuring a layer of lithium-containing compound (lithium garnet), which acts as a solid electrolyte between the two electrodes. Lithium garnet is one of the materials with the highest known conductivity for lithium ions.
“During production, we made sure that the solid electrolyte layer obtained a porous surface,” says Jan van den Broek, a master’s student in Rupp’s group. The researchers then applied the material of the negative pole in a viscous form, allowing it to seep into the pores. Finally, the scientists tempered the battery at 100C. “With a liquid or gel electrolyte, it would never be possible to heat a battery to such high temperatures,” says van den Broek. Thanks to the trick with the pores, the researchers were able to significantly enlarge the contact area between the negative pole and the solid electrolyte, which ultimately means that the battery can be charged faster.
Batteries produced like this could theoretically operate at a normal ambient temperature. But they work best at 95C and above at the current development state. “The lithium ions can then move around better in the battery,” says Afyon. This characteristic could be put to use in battery storage power plants, which store excess energy and deliver it later as needed. “Today, the waste heat that results from many industrial processes vanishes unused,” says Afyon. “By coupling battery power plants with industrial facilities, you could use the waste heat to operate the storage power plant at optimal temperatures.”
SEM image from an interface-engineered all-solid-state battery based on c-Li6.25Al0.25La3Zr2O12 and nanograined Li4Ti5O12 electrode obtained after 25 charge/discharge cycles, displaying the solid electrolyte and the electrode surface.
“In this work we have for the first time built a whole lithium-ion battery with a solid lithium garnet electrolyte and a solid minus pole made of an oxide-based material. Thus, we have shown that it is possible to build whole batteries based on lithium garnet,” says ETH Professor Rupp. Thanks to this solid electrolyte one can not only operate batteries at higher temperatures, but also build thin-film batteries, that can even be directly placed on silicon chips.
“These thin-film batteries could revolutionise the energy supply of portable electronic devices,” says Rupp. She and her team will pursue this approach in further research. To this end, they have also collaborated with industrial partners as well as with the Paul Scherrer Institute and with Empa. The immediate next step is to optimise the battery, with a particular focus on further increasing the conductivity of the electrode-electrolyte interface. https://www.ethz.ch/en/news-and-events/eth-news/news/2016/08/all-solid-state-lithium-ion-batteries.html
http://dx.doi.org/10.1002/aenm.201600736
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