Polarised Raman spectroscopy results for TIPS pentacene sample. Comparison of measured (top) polarised Raman data with the best fitting simulated results (bottom). The intensities of the 1374 cm−1 and 1576 cm−1 modes measured with tilts of both 0° and 30° around the -axis are considered. In each plot the normalised intensity of the Raman peak is plotted against the polariser angle (θP) and analyser angle (θA).
New technology could revolutionize printed electronics by enabling high quality semiconducting molecular crystals to be directly spray-deposited on any surface. University of Surrey and National Physical Laboratory’s research allows to convert organic semiconducting inks into isolated crystals through a scalable process, suitable for a wide range of molecules. The research has a direct impact on printed electronic applications for flexible circuits, advanced photodetector arrays, chemical and biological sensors, robotic skin tensile sensors, x-ray medical detectors, light emitting transistors and diodes, and miniature lasers.
Has the time come to replace traditionally used silicon with printable organic semiconductor inks? University of Surrey scientists believe so, especially for future electronics that need to be flexible, lightweight, wearable and low-cost. Single crystal semiconductors, such as silicon, have been at the forefront of scientific interest for more than 70 years, serving as the backbone of electronic devices. Inorganic single crystals are typically grown from a melt at very high temperatures, in special chambers filled with inert gas, using time-consuming and energy intensive processes. A new class of crystalline materials, called organic semiconductors, can also be grown as single crystals, but in a very different way, using solution-based methods at room temperature in air, opening up the possibility of large-scale production of inexpensive electronics, targeting numerous applications ranging from field effect transistors and LEDs to medical xray detectors and miniature lasers.
The key aspect is in combining the advantages of antisolvent crystallization and solution shearing. The crystals’ size, shape and orientation are then controlled by the spay angle and distance to the substrate, which govern the spray droplets’ impact onto the antisolvent’s surface. These crystals are high quality structures, as confirmed by a combination of characterisation techniques, eg polarised optical and scanning electron microscopy, x-ray diffraction, polarised Raman spectroscopy and field-effect transistor tests. “This method is a powerful, new approach for manufacturing organic semiconductor single crystals and controlling their shape and dimensions,” said Dr Maxim Shkunov, Advanced Technology Institute at the University of Surrey.
“If we look at silicon, it takes almost 15000C to grow semiconductor grade crystals, while steel spoons will melt at this temperature, and it will fetch a very hefty electric bill for just 1 kg of silicon, same as for running a tea kettle for over 2 days non-stop. And then, you would need to cut and polish those silicon ‘boules’ into wafers. “We can make single crystals in a much simpler way, entirely at room temperature with a £5 artist spray brush. With a new class of organic semiconductors based on carbon atoms, we can spray-coat organic inks onto anything, and get more or less the right size of crystals for our devices right away.”
Dr Maxim Shkunov continued: “The trick is to cover the surface with a non-solvent so that semiconductor molecules float on top and self-assemble into highly ordered crystals. We can also beat silicon by using light emitting molecules to make lasers, for example, – something you can’t do with traditional silicon. This molecular crystals growth method opens amazing capabilities for printable organic electronics.” http://www.alphagalileo.org/ViewItem.aspx?ItemId=170130&CultureCode=en
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