Structural comparison of penlandite with hydrogenases. (a) Crystal structure of Ni4.5Fe4.5S8. The nickel and iron sites (brown) share the same positions within the crystal and are bridged by sulfur (yellow). (b) Active site of the [FeNi]-hydrogenase (PDB: 4U9H) as well as (c) [FeFe]-hydrogenase (X=NH, PDB: 1HFE).
Mineral pentlandite works just as efficient as expensive platinum electrodes commonly used today. In contrast to platinum, pentlandite is affordable and found frequently on Earth. In addition to platinum, there are numerous other substances that can catalyse the reaction of water to hydrogen and oxygen and do not contain any precious metals. Among such compounds are the so-called metal chalcogenides...
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