
Scheme of the local surface chemistry modification and AuNPs tracking approach. (a) Ag nanoantennas were modified overnight with 1 mM ethanolic solution of 4-NTP. Several ethanol/water washing steps were performed on each sample. (b) 4-NTP-coated antennas were immersed in 0.1 M HCl solution and illuminated for different times at their LSPR wavelength (633 nm) with a power density of 1 W cm−2. Samples were rinsed with water and immediately dipped in the activated AuNP suspension. (c) AuNPs (15 nm) coated with 11-mercaptoundecanoic acid (MUA) as a capping layer were suspended in HEPES buffer and mixed with 1 mM EDC and 1 mM NHS, and left to react for 30 min followed by two purification centrifugation steps...
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