chemical reactions tagged posts

Scientists finally crack down Nature’s most Common Chemical Bond

A catalyst (center) based on iridium (blue ball) can snip a hydrogen atom (white balls) off a terminal methyl group (upper and lower left) to add a boron-oxygen compound (pink and red) that is easily swapped out for more complicated chemical groups. The reaction works on simple hydrocarbon chains (top reaction) or more complicated carbon compounds (bottom reaction). The exquisite selectivity of this catalytic reaction is due to the methyl group (yellow) that has been added to the iridium catalyst. The black balls are carbon atoms; red is oxygen; pink is boron. (UC Berkeley image by John Hartwig)

Carbon-hydrogen bonds in hydrocarbon molecules have resisted functionalization until now...

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Energy researchers Break the Catalytic Speed limit

Dynamics Wave
A new discovery by University of Minnesota and University of Massachusetts Amherst researchers could increase the speed and lower the cost of thousands of chemical processes used in developing fertilizers, foods, fuels, plastics, and more.

A team of researchers from the University of Minnesota and University of Massachusetts Amherst has discovered new technology that can speed up chemical reactions 10,000 times faster than the current reaction rate limit. These findings could increase the speed and lower the cost of thousands of chemical processes used in developing fertilizers, foods, fuels, plastics, and more.

In chemical reactions, scientists use what are called catalysts to speed reactions...

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An Enzyme Enigma discovered in the Abyss

Verrucosispora maris, the bacteria in which the enzyme was found. Credit: P. Race

Verrucosispora maris, the bacteria in which the enzyme was found. Credit: P. Race

Scientists at the Universities of Bristol and Newcastle have uncovered the secret of the ‘Mona Lisa of chemical reactions’ – in a bacterium that lives at the bottom of the Pacific Ocean. It is hoped the discovery could lead to the development of new antibiotics and other medical treatments. The Diels-Alder reaction, discovered by Nobel Prize-wining chemists Otto Diels and Kurt Alder, is one of the most powerful chemical reactions known, and is used extensively by synthetic chemists to produce many important molecules, including antibiotics, anti-cancer drugs and agrochemicals.

However, there has been much debate and controversy about whether nature uses the reaction to produce its own useful molecules...

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