fuel cells tagged posts

Pure platinum with thin fixed foils of yttrium have been used to create the new nanoalloys that are ten times as effective as pure platinum in fuel cells. Credit: Mia Halleröd Palmgren CC BY 3.0

A new type of nanocatalyst can result in the long-awaited commercial breakthrough for fuel cell cars. Research results from Chalmers University of Technology and Technical University of Denmark show that it is possible to significantly reduce the need for platinum, a precious and rare metal, by creating a nanoalloy using a new production technique. The technology is also well suited for mass production.

“A nano solution is needed to mass-produce resource-efficient catalysts for fuel cells. With our method, only 1/10 as much platinum is needed for the most demanding reactions...

Schematic diagram of the oxygen reduction reaction (reduction of O2 into H2O) on the Pt(110) surface of the PtPb/Pt nanoplates, with purple representing Pt atoms and orange representing Pb atoms. Credit: Brookhaven National Laboratory

New platinum-based catalysts with tensile surface strain could improve fuel cell efficiency. Fuel cells are a promising technology for clean and efficient electrical power generation, but their cost, activity, and durability are key challenges to commercialization. Today’s fuel cells use expensive platinum (Pt)-based nanoparticles as catalysts to accelerate the reactions involved in converting the chemical energy from renewable fuels -such as hydrogen, methanol, and ethanol – into electrical energy...

Bottom: Platinum atoms attached to layers of lithium cobalt oxide contract when electricity is applied, boosting platinum catalytic efficiency by 90 percent. Top: Removing electrons separates the atoms and lowers efficiency by 40 percent. (1 Ångstrom = 0.1 nanometer) (Image credit: Haotian Wang)

A nanosize squeeze can significantly boost the performance of platinum catalysts that help generate energy in fuel cells, according to a new study by Stanford scientists. The team bonded a platinum catalyst to a thin material that expands and contracts as electrons move in and out, and found that squeezing the platinum a fraction of a nanometer nearly doubled its catalytic activity.

“In this study, we present a new way to fine...

Modeling how methanol interacts with platinum catalysts inside fuel cells in realistic environments becomes even more complicated because distances between the atoms can change as molecules dance near the charged surface. Credit: Manos Mavrikakis

Using a unique combination of advanced computational methods, University of Wisconsin-Madison chemical engineers have demystified some of the complex catalytic chemistry in fuel cells – an advance that brings cost-effective fuel cells closer to reality. “Understanding reaction mechanisms is the first step toward eventually replacing expensive platinum in fuel cells with a cheaper material,” says Prof. Manos Mavrikakis.

Fuel cells generate electricity by combining electrons and protons — provided by a chemical fuel such as methanol – with oxygen fr...