Metal Organic Frameworks tagged posts

Simultaneous photocatalytic hydrogen generation and dye degradation using a visible light active metal-organic framework.
Credit: Alina-Stavroula Kampouri/EPFL

Researchers have developed a photocatalytic system based on a material in the class of metal-organic frameworks. The system can be used to degrade pollutants present in water while simultaneously producing hydrogen that can be captured and used further.

Some of the most useful and versatile materials today are the metal-organic frameworks (MOFs). MOFs are a class of materials demonstrating structural versatility, high porosity, fascinating optical and electronic properties, all of which makes them promising candidates for a variety of applications, including gas capture and separation, sensors, and photocatalysis.

Because MOFs are so...

Individual crystals of synthetic zhemchuzhnikovite, prepared by Igor Huski?, McGill University. Credit: Igor Huski?, Friš?i? Research Group, McGill University

A surprising discovery reveals that MOFs also exist in nature – albeit in the form of rare minerals found so far only in Siberian coal mines. Metal-organic frameworks are human-made materials introduced in the 1990s, and researchers are working on ways to use them as molecular sponges for applications such as H storage, C sequestration, or photovoltaics.

The finding “completely changes the normal view of these highly popular materials as solely artificial, ‘designer’ solids,” says Tomislav Friščić, an associate professor of chemistry at McGill University in Montreal...

The 3D structure of the metal-organic framework used in this study. The nanopores are represented as yellow balls. Credit: Image courtesy of KU Leuven

Metal-organic frameworks (MOFs) are a new type of materials with nanoscale pores. Bioscience engineers have now developed an alternative method that produces these materials in the form of very thin films, so that they can easily be used for high-tech applications such as microchips.

Metal-organic frameworks (MOFs) are a recently developed type of materials that consist of a nanoporous grid of both organic molecules and metal ions. MOFs take shape as the organic molecules push the metal ions apart, so that a regular pattern of tiny holes or nanopores develops. The size of the pores can be tuned at the nanoscale level...

Over time, the zinc ions in MOF-5 (pink solutions) get replaced with cobalt ions, (blue solutions) demonstrating the dynamics of metal organic frameworks. Credit: American Chemical Society.

MOF’s have many potential apps: antimicrobial agents, H-storage materials and solar-cell components.

Despite their rigid-sounding name, MOF structures are also dynamic – much more so than previously thought. This discovery could lead to the synthesis of brand-new types of materials. As the name implies, MOFs are composed of networks of organic (carbon-based) compounds interspersed with metal ions. Many different combinations of metals and organic components exist, but much of what we know about these systems comes from a zinc and benzene di-acid framework called MOF5...