a, Preparation of InP cores and InP/ZnSe/ZnS QDs with different morphology and shell thickness. The amounts of Se precursor for QD-1, QD-2 and QD-3 were 0.6 mmol, 1.2 mmol and 2.0 mmol, respectively, per 10 ml of solvent. The estimated size, based on inductively coupled plasma-atomic emission spectroscopy (ICP-AES) data, was projected on the STEM image of each QD. b, Ultraviolet–visible absorption spectra of the aliquots, taken during the InP core synthesis. a.u., arbitrary units. c, Photoluminescence spectra of QD-1′ (prepared without HF addition), QD-1, QD-2, QD-3, QD-1R, QD-2R and QD-3R. Inset, photograph of QD-1′ (no HF) and QD-3 taken under 365 nm illumination. d–i, STEM images of QD-1, QD-1R, QD-2, QD-2R, QD-3 and QD-3R (scale bar, 20 nm)...Read More
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