triplet-triplet annihilation tagged posts

Achieving photochemical upconversion in a solid state is a step closer to reality, thanks to a new technique that could unlock vital innovations in renewable energy, water purification and advanced healthcare.

Exciton Science researchers based at UNSW Sydney have demonstrated that a key stage in the upconversion process can be achieved in the solid state, making it more likely that a functioning device can be manufactured at commercial scale. Possible applications include hydrogen catalysis and solar energy generation.

Their work has been published in the high-impact journal ACS Energy Letters and is likely to drive major changes in the approach of scientists around the world researching this challenging but potentially transformational field.

Professor Tim Schmidt of UNSW Sy...

Photon upconversion: Energy transfer between the molecules is based on electron exchange (Dexter electron transfer). Credit: Illustration: Michael Oldenburg

The upconversion of photons allows for a more efficient use of light: 2 photons are converted into a single photon having higher energy. Researchers at KIT now showed for the first time that the inner interfaces between surface-mounted metal-organic frameworks (SURMOFs) are suited perfectly for this purpose – they turned green light blue. The result opens up new opportunities for optoelectronic applications such as solar cells or LEDs.

Metal-organic frameworks (MOFs) are highly ordered molecular systems that consist of metallic clusters and organic ligands...