Thermoelectric Paint enables Walls to convert Waste Heat into Electricity

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thermoelectric paint

Thermoelectric paint being applied to an alumina hemisphere. The paint provides closer contact with the heat-emitting surface than conventional planar thermoelectric devices do. Credit: Park et al. ©2016 Nature Communications

Paint these days is becoming much more than it used to be. Already researchers have developed photovoltaic paint, which can be used to make “paint-on solar cells” that capture the sun’s energy and turn it into electricity. Now in a new study, researchers have created thermoelectric paint, which captures waste heat from hot painted surfaces and converts it into electrical energy.

“I expect that the thermoelectric painting technique can be applied to waste heat recovery from large-scale heat source surfaces, such as buildings, cars, and ship vessels,” said Jae Sung Son, Ulsan National Institute of Science and Technology (UNIST).
“For example, the temperature of a building’s roof and walls increases to more than 50 °C in the summer,” he said. “If we apply thermoelectric paint on the walls, we can convert huge amounts of waste heat into electrical energy.”

The thermoelectric paint looks very different than conventional thermoelectric materials, which are typically fabricated as flat, rigid chips. These devices are then attached to irregular-shaped objects that emit waste heat, such as engines, power plants, and refrigerators. However, the incomplete contact between these curved surfaces and the flat thermoelectric generators results in inevitable heat loss, decreasing the overall efficiency.
In the new study, Sung Hoon Park et al., from UNIST, KIST and the Korea Electrotechnology Research Institute, have addressed this issue of incomplete contact by demonstrating that the thermoelectric paint easily adheres to the surface of virtually any shape.

The thermoelectric paint contains the thermoelectric particles bismuth telluride (Bi2Te3), commonly used in conventional thermoelectric devices. They also added molecular sintering aids which, upon heating, cause the thermoelectric particles to coalesce, increasing the density of these particles in the paint along with their energy conversion efficiency (the ZT values are up to 0.67 for n-type and 1.21 for p-type particles). The thermoelectric paint can be painted onto a variety of curved heat-emitting surfaces. After sintering for 10 minutes at 450 °C, the painted layers form a uniform film about 50 micrometers thick.

Tests showed devices painted with thermoelectric paint had high output power density (4 mW/cm2 for in-plane type devices and 26.3 mW/cm2 for through-plane type devices). These values are competitive with conventional thermoelectric materials and better than all thermoelectric devices based on inks and pastes.

Besides traditional thermoelectric applications they expect it to have the potential to be used as wearable thermoelectric energy harvesters. The technology developed here could also be used in 3D printed electronics and painted electronic art. “We are planning on developing room-temperature-processable, air-insensitive, and scalable thermoelectric paint and painting processes for practical applications,” Son said.
http://phys.org/news/2016-11-thermoelectric-enables-walls-electricity.htmljCp