Synthetic process of metal-organic framework nanosheet array. Figure 1 Metal salts and substrate are firstly mixed together in an aqueous solution, and then introduces the organic ligand. Next, the MOF nanosheet array grows on the surface of substrate via a dissolution-crystallization mechanism.
UNSW Sydney chemists have invented a new, cheap catalyst for splitting water with an electrical current to efficiently produce clean hydrogen fuel. The technology is based on the creation of ultrathin slices of porous metal-organic complex materials coated onto a foam electrode, which have are highly conductive of electricity and active for splitting water. “Splitting water usually requires two different catalysts, but our catalyst can drive both of the reactions required to separate water into its 2 constituents, oxygen and hydrogen,” says Associate Professor Chuan Zhao.
“Our fabrication method is simple and universal, so we can adapt it to produce ultrathin nanosheet arrays of a variety of these materials, called metal-organic frameworks. “Compared to other water-splitting electro-catalysts reported to date, our catalyst is also among the most efficient,” he says. The catalysts developed at UNSW are made of abundant, non-precious metals like nickel, iron and copper. They belong to a family of versatile porous materials called metal organic frameworks, MOFs, which have a wide variety of other potential applications.
Until now, MOFs were considered poor conductors and not very useful for electrochemical reactions. Conventionally, they are made in the form of bulk powders, with their catalytic sites deeply embedded inside the pores of the material, where it is difficult for the water to reach. By creating nanometre-thick arrays of metal-organic frameworks, Zhao’s team was able to expose the pores and increase the surface area for electrical contact with the water.
“With nanoengineering, we made a unique metal-organic framework structure that solves the big problems of conductivity, and access to active sites,” says Zhao. “It is ground-breaking. We were able to demonstrate that metal-organic frameworks can be highly conductive, challenging the common concept of these materials as inert electro-catalysts.” Metal-organic frameworks have potential for a large range of applications, including fuel storage, drug delivery, and carbon capture. The UNSW team’s demonstration that they can also be highly conductive introduces a host of new applications for this class of material beyond electro-catalysis. https://www.nature.com/articles/ncomms15341
http://www.chemistry.unsw.edu.au/news-events/news/2017/06/new-water-splitting-materials-cheap-production-clean-energy
Recent Comments