Category Chemistry/Nanotechnology

The folds of 3-D graphene make mesopore channels that work with the surface’s micropores to increase the material’s supercapacitive properties.

Tiny dents in the surface of graphene greatly enhances its potential as a supercapacitor. Even better, it can be made from CO2. A material scientist at Michigan Technological University invented a novel approach to take carbon dioxide and turn it into 3D graphene with micropores across its surface. The conversion of carbon dioxide to useful materials usually requires high energy input due to its ultrahigh stability. However, materials science professor Yun Hang Hu and his research team created a heat-releasing reaction between carbon dioxide and sodium to synthesize 3D surface-microporous graphene.

“3D surface-microporous graphene is a brand-new ma...

Confining metal-halide perovskites in nanoporous thin films. Science Advances, 2017; 3 (8): e1700738 DOI: 10.1126/sciadv.1700738 Foto: Foto Ruhrgebiet / fotolia.com

The color of the light emitted by an LED can be tuned by altering the size of their semiconductor crystals. Ludwig-Maximilians-Universitaet (LMU) in Munich researchers have now found a clever and economical way of doing just that, which lends itself to industrial-scale production. Unlike incandescent lightbulbs, light-emitting diodes produce light of a defined color within the spectral range from the infrared to the ultraviolet. The exact wavelength of the emission is determined by the chemical composition of the semiconductor, the crucial component...

MIT researchers have developed a new design system that catalogues the physical properties of a huge number of tiny cube clusters. These clusters can then serve as building blocks for larger printable objects. Credit: Computational Fabrication Group at MIT

Designing the microstructure of printed objects. Today’s 3D printers have a resolution of 600 dots per inch, ie they could pack a billion tiny cubes of different materials into a volume that measures just 1.67 cubic inches. Such precise control of printed objects’ microstructure gives designers commensurate control of the objects’ physical properties – eg. density or strength, or the way they deform when subjected to stresses...

Carbon Nitride Aerogels for the Photoredox Conversion of Water. Angewandte Chemie International Edition, 2017; DOI: 10.1002/anie.201705926 © Wiley-VCH

Carbonitride aerogels mediate the photocatalytic conversion of water. Nanochemistry meets macrostructures: Chinese scientists report the synthesis of a macroscopic aerogel from carbonitride nanomaterials which is an excellent catalyst for the water-splitting reaction under visible-light irradiation. The study published in the journal Angewandte Chemie adds new opportunities to the material properties of melamine-derived carbonitrides.

Melamine can be polymerized with formaldehyde to give a highly durable and light resin, but it can also condensed to form nanostructures of carbonitride materials...