Category Chemistry/Nanotechnology

Ruthenium Rules for New Fuel Cells

Single-Atomic Ruthenium Catalytic Sites on Nitrogen-Doped Graphene for Oxygen Reduction Reaction in Acidic Medium. ACS Nano, 2017; DOI: 10.1021/acsnano.7b02148

Single-Atomic Ruthenium Catalytic Sites on Nitrogen-Doped Graphene for Oxygen Reduction Reaction in Acidic Medium. ACS Nano, 2017; DOI: 10.1021/acsnano.7b02148

Project disperses single atoms on graphene to match platinum standard. Rice University scientists have fabricated a durable catalyst for high-performance fuel cells by attaching single ruthenium atoms to graphene. Catalysts that drive the oxygen reduction reaction that lets fuel cells turn chemical energy into electricity are usually made of platinum, which stands up to the acidic nature of the cell’s charge-carrying electrolyte. But platinum is expensive.

The ruthenium-graphene combination may fit the bill...

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New Class of ‘Soft’ Semiconductors could Transform HD displays

Single nanowires shown emitting different colors. The top panel shows a cesium lead bromide (CsPbBr3)-cesium lead chloride (CsPbCl3) heterojunction simultaneously emitting green and blue lights, respectively, under UV excitation. The bottom panel shows a cesium lead iodide (CsPbI3)-cesium lead bromide-cesium lead chloride configuration emitting red, green, and blue lights, respectively. Credit: Letian Dou/Berkeley Lab and Connor G. Bischak/UC Berkeley

Single nanowires shown emitting different colors. The top panel shows a cesium lead bromide (CsPbBr3)-cesium lead chloride (CsPbCl3) heterojunction simultaneously emitting green and blue lights, respectively, under UV excitation. The bottom panel shows a cesium lead iodide (CsPbI3)-cesium lead bromide-cesium lead chloride configuration emitting red, green, and blue lights, respectively. Credit: Letian Dou/Berkeley Lab and Connor G. Bischak/UC Berkeley

A new type of semiconductor may be coming to a high-definition display near you. Scientists at Berkeley Lab have shown that a class of semiconductor called halide perovskites is capable of emitting multiple, bright colors from a single nanowire at resolutions as small as 500 nanometers...

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New Sensors could enable more Affordable Detection of Pollution, Diseases

Versatile Barometer Biosensor Based on Au@Pt Core/Shell Nanoparticle Probe

Versatile Barometer Biosensor Based on Au@Pt Core/Shell Nanoparticle Probe

When it comes to testing for cancer, environmental pollution and food contaminants, traditional sensors can help. The challenges are that they often are bulky, expensive, non-intuitive and complicated. Now, one team reports in ACS Sensors that portable pressure-based detectors coupled with smartphone software could provide a simpler, more affordable alternative while still maintaining sensitivity.

Current disease and contamination sensors require expensive readout equipment or trained personnel. Yuehe Lin, Yong Tang and colleagues propose a new detection system based on pressure changes...

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Chemical Solution to Shrink Digital Data Storage

CWRU chemists developed a space-saving method to store digital data optically, using four-symbol, or quaternary code. The four symbols are the absence of color and three colors -- fluorescent green, ultramarine and cyan -- produced when dyes contained in a common polymer are exposed to heat, ultraviolet light or both. Credit: Emily Pentzer

CWRU chemists developed a space-saving method to store digital data optically, using four-symbol, or quaternary code. The four symbols are the absence of color and three colors — fluorescent green, ultramarine and cyan — produced when dyes contained in a common polymer are exposed to heat, ultraviolet light or both. Credit: Emily Pentzer

Chemists at Case Western Reserve University have found a way to possibly store digital data in half the space current systems require. From supercomputers to smartphones, the amount of data people generate and collect continues to grow exponentially, and the need to store all that information grows with it. To reduce storage space, engineers have traditionally used existing technology but made it smaller...

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