Category Chemistry/Nanotechnology

Researchers find 1st compelling evidence of new property known as ‘Ferroelasticity’ in Perovskites

1, Schematic shows a perovskite sample (black) examined by the photothermal induced resonance technique. When the sample absorbs pulses of light (depicted as disks in purple cones), the sample expands rapidly, causing the cantilever of an atomic force microscope (AFM) to vibrate like a struck tuning fork. The cantilever’s motion, which is detected by reflecting the AFM laser light (red) off the AFM detector, provides a sensitive measure of the amount of light absorbed. Credit: NIST 2. Image recorded by an atomic force microscope reveals the topography of a polycrystalline sample of the perovskite, including the boundaries between crystals. Credit: NIST 3. Illustration shows that in response to an applied stress, such as bending, the boundaries of the ferroelastic domains (red and blue regions depict domains oriented in different directions) become bigger or smaller. Credit: NIST

1, Schematic shows a perovskite sample (black) examined by the photothermal induced resonance technique. When the sample absorbs pulses of light (depicted as disks in purple cones), the sample expands rapidly, causing the cantilever of an atomic force microscope (AFM) to vibrate like a struck tuning fork. The cantilever’s motion, which is detected by reflecting the AFM laser light (red) off the AFM detector, provides a sensitive measure of the amount of light absorbed.  2. Image recorded by an atomic force microscope reveals the topography of a polycrystalline sample of the perovskite, including the boundaries between crystals. 3...

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Synthesis of H2: Novel Method sets Benchmark for Platinum-free Electrocatalysts

a) Synthetic scheme of MoNi4 electrocatalyst supported by the MoO2 cuboids on nickel foam; b) polarization curves of the MoNi4 electrocatalyst supported by the MoO2 cuboids, pure Ni nanosheets and MoO2 cuboids on the nickel foam; c) calculated adsorption free energy diagram for the Tafel step. Credit: Image courtesy of Technische Universitaet Dresden

a) Synthetic scheme of MoNi4 electrocatalyst supported by the MoO2 cuboids on nickel foam; b) polarization curves of the MoNi4 electrocatalyst supported by the MoO2 cuboids, pure Ni nanosheets and MoO2 cuboids on the nickel foam; c) calculated adsorption free energy diagram for the Tafel step.
Credit: Image courtesy of Technische Universitaet Dresden

A new paper from cfaed’s Chair for Molecular Functional Materials describes a new approach to revolutionize the production of molecular hydrogen. In many of the approaches for hydrogen production, the electrocatalytic hydrogen evolution reaction (HER) from water splitting is the most economical and effective route for the future hydrogen economy...

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Graphene-Nanotube Hybrid boosts Lithium Metal Batteries

1. Lithium metal coats the hybrid graphene and carbon nanotube anode in a battery created at Rice University. The lithium metal coats the three-dimensional structure of the anode and avoids forming dendrites. Courtesy of the Tour Group. 2. A graphic shows carbon nanotubes covalently bonded to a graphene substrate. The material created at Rice University is being tested as an anode for high-capacity lithium metal batteries. Courtesy of the Tour Group - See more at: http://news.rice.edu/2017/05/18/graphene-nanotube-hybrid-boosts-lithium-metal-batteries-2/#sthash.eX5HvXSE.dpuf 3. An electron microscope image shows a carbon nanotube evenly coated with lithium metal. Tests on the graphene-carbon nanotube anode created at Rice University show it resists the formation of lithium dendrites that can damage batteries. Courtesy of the Tour Group

1. Lithium metal coats the hybrid graphene and carbon nanotube anode in a battery created at Rice University. The lithium metal coats the three-dimensional structure of the anode and avoids forming dendrites. Courtesy of the Tour Group.
2. A graphic shows carbon nanotubes covalently bonded to a graphene substrate. The material created at Rice University is being tested as an anode for high-capacity lithium metal batteries. Courtesy of the Tour Group – See more at: http://news.rice.edu/2017/05/18/graphene-nanotube-hybrid-boosts-lithium-metal-batteries-2/#sthash.eX5HvXSE.dpuf
3. An electron microscope image shows a carbon nanotube evenly coated with lithium metal...

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New Water-based, Recyclable Membrane Filters all types of Nanoparticles

A self-assembling membrane for water purification. Credit: Image courtesy of Weizmann Institute of Science

A self-assembling membrane for water purification. Credit: Image courtesy of Weizmann Institute of Science

Separation technology is at the heart of water purification, sewage treatment, and materials reclamation, as well as numerous basic industrial processes. Membranes are used to separate out the smallest nanoscale particles, and even molecules and metal ions. Prof. Boris Rybtchinski and his group of the Weizmann Institute of Science’s Department of Organic Chemistry have developed a new type of membrane that could extend the life of a separation system, lower its cost and, in some cases, increase its efficiency as well.

The membranes Prof...

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