Category Chemistry/Nanotechnology

A hydrogen bond forms between a propellane (lower molecule) and the carbon monoxide functionalized tip of an atomic force microscope. The measured forces and the distance between the oxygen atom at the AFM tip and the propellane’s hydrogen atoms correspond precisely to the calculations. Credit: University of Basel, Department of Physics

Scientists have succeeded in studying the strength of hydrogen bonds in a single molecule using an atomic force microscope, AFM. Hydrogen is the most common element in the universe and is an integral part of almost all organic compounds. H-bonds are responsible for specific properties of proteins or nucleic acids and, for example, also ensure that water has a high boiling temperature...

Illinois professor Paul Braun and Hailong Ning, the director of research and development at Xerion Advanced Battery Corporation, led a research team that developed a method for directly electroplating lithium-ion battery cathodes. Credit: Photo by L. Brian Stauffer

The process that makes gold-plated jewelry or chrome car accents is now making powerful lithium-ion batteries. Researchers at the University of Illinois, Xerion Advanced Battery Corporation and Nanjing University in China developed a method for electroplating lithium-ion battery cathodes, yielding high-quality, high-performance battery materials that could open the door to flexible and solid-state batteries.

Traditional lithium-ion battery cathodes use lithium-containing powders formed at high temperatures...

The authors observed in real-time the transformation of a HfO2 nanorod from its room temperature to tetragonal phase, at 1000° less than its bulk temperature. Nanorod surfaces and twin boundary defects (pictured here) serve to kinetically trap this phase.

Materials research creates potential for improved computer chips and transistors. The inorganic compound hafnium dioxide commonly used in optical coatings has several polymorphs, including a tetragonal form with highly attractive properties for computer chips and other optical elements. However, because this form is stable only at temperatures above 3100F – scientists have had to make do with its more limited monoclinic polymorph. Until now...

This visualisation shows layers of graphene used for membranes. Credit: University of Manchester

In a battery system, electrodes containing porous graphene scaffolding offer a substantial improvement in both the retention and transport of energy, a new study reveals. Usually, techniques to improve the density of stored charge conflict with those that aim to improve the speed at which ions can move through a material. Nanostructured materials have shown extraordinary promise for electrochemical energy storage, but these materials are usually limited to laboratory cells with ultrathin electrodes and very low mass loadings.

Hongtao Sun et al. overcome this obstacle by incorporating holey graphene into a niobium pentoxide electrode. The nanopores facilitate rapid ion transport...