Category Chemistry/Nanotechnology

This is an illustration of proton hopping during catalytic reaction. Credit: Waseda University

Simpler process and higher efficiency creates great expectations for consumer market. Waseda University researchers have developed a new method for producing hydrogen, which is fast, irreversible, and takes place at much lower temperature using less energy. This innovation will improve fuel cell systems for automobiles and homes. Hydrogen has normally been extracted from methane and steam using a nickel catalyst at temperatures of over 700°C. However, the high temperature creates major challenges for widespread use.

The group led by Professor Yasushi Sekine, Waseda developed a method which allows hydrogen extraction at temperatures as low as 150~200°C...

Researchers have developed a specialized type of glowing metal organic framework, or LMOF (molecular structure at center), that is designed to detect and remove heavy-metal toxins from water. At upper left, mercury (Hg) is taken in by the LMOF. The graph at lower left shows how the LMOF’s fluorescence is turned off as it binds up the mercury. Its properties make this LMOF useful for both detecting and trapping heavy-metal toxins. Credit: Rutgers University

X-ray study explores atomic structure of tiny traps for heavy metals. Tiny, glowing crystals that detect and capture heavy-metal toxins such as lead and mercury could prove to be a powerful new tool in locating and cleaning up contaminated water sources...

Ketone (fluorenone) polymer can fix hydrogen via simple electrolytic hydrogenation in water at room temperature and release hydrogen when heated to 80 degrees C. Credit: Waseda University

Polymer addresses safety and energy loss. A Waseda University (Tokyo) research group has developed a polymer which can store hydrogen in a light, compact and flexible sheet, and is safe to touch even when filled with hydrogen gas. The conventional methods of storing and carrying hydrogen were accompanied by safety risks such as explosions. Recently, hydrogen-absorbing organic compounds have been studied as storage materials, for their ability to stably store and release hydrogen through chemical bonding...

The schematic image of molecular structure shows trapped gas (shown in green) in the nanospace of MOF/PCP. The materials acting like sponge capture, store, and release gas molecules. Credit: Copyright : Ryotaro MATSUDA

Prof. Ryotaro Matsuda, Nagoya University, and Prof. Susumu Kitagawa, Kyoto University, won the contest “Air Liquide Essential Molecules Challenge.” For the first edition of the challenge, their project was selected as 1 in 3 from a total of 130 scientific proposals submitted by academic teams, R&D departments, and start-ups from 25 countries.

Essential molecules, eg. O2, N2, C2H2, CO, CO2, NO, NO2, and/or noble gases, are fundamental resources for our cultural lives...