Category Chemistry/Nanotechnology

Hybrid Perovskites: Super-Ion Building Blocks

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Scientists discovered how to control a material’s properties and stability to develop next-generation solar cells based on newly discovered hybrid perovskites (atomic structure shown above). Simulations revealed that hybrid perovskites could be viewed as super-alkali halides. The schematic illustrates a hybrid perovskite structure where the super halogens are the blue tetrahedrons, the metal atoms are green, and the alkali cation is in the middle (gray structure with pink and black atoms). Journal of Materials Chemistry A

Lead-free, more efficient solar cells and other optoelectronics devices will likely be based on a family of materials known as hybrid perovskites...

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Something Deep within: Nanocrystals Grown in Nanowires

Top: High-resolution electron microscopy images of a nickel silicide rhombic nanocrystal embedded in a silicon nanowire prepared with gold silicide used as a catalyst. The images demonstrate the intimate interactions that arise at the interfaces of these nanomaterials. Bottom: The physical properties that arise from such complex nano-systems could be used in next-generation photodetectors, lasers, and transistors.

Top: High-resolution electron microscopy images of a nickel silicide rhombic nanocrystal embedded in a silicon nanowire prepared with gold silicide used as a catalyst. The images demonstrate the intimate interactions that arise at the interfaces of these nanomaterials. Bottom: The physical properties that arise from such complex nano-systems could be used in next-generation photodetectors, lasers, and transistors.

Scientists have tailored extremely small wires that carry light and electrons which could open up a potential path to smaller, lighter, or more efficient devices. This development could lead to highly tailored nanowires for new classes of high-performance, energy-efficient computing, communications, and environmental and medical sensing systems...

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Breakthrough Solar cell captures CO2 and Sunlight, produces burnable Fuel

Simulated sunlight powers a solar cell that converts atmospheric carbon dioxide directly into syngas. Credit: University of Illinois at Chicago/Jenny Fontaine

Simulated sunlight powers a solar cell that converts atmospheric carbon dioxide directly into syngas. Credit: University of Illinois at Chicago/Jenny Fontaine

1,000-fold improved chemistry leads to ‘artificial leaf’ that makes Syngas. A provisional patent application has been filed by the by University of Illinois researchers. Unlike conventional solar cells, which convert sunlight into electricity that must be stored in heavy batteries, the new device essentially does the work of plants, converting atmospheric carbon dioxide into fuel, solving 2 crucial problems at once. A solar farm of such “artificial leaves” could remove significant amounts of carbon from the atmosphere and produce energy-dense fuel efficiently.

“The new solar cell is not photovoltaic – it’s photosynthetic,” says Amin ...

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New Material could Advance Superconductivity

At center, in green, is the new three-atom hydrogen 'chain.' It is surrounded by several 'normal' two-atom molecules of hydrogen, also in green. The new chain configuration appears in the new material NaH7, which was produced under high pressure and high temperature conditions. The new material could change the superconductivity landscape and be useful for hydrogen storage in hydrogen fuel cells. Credit: Image courtesy Duck Young Kim

At center, in green, is the new three-atom hydrogen ‘chain.’ It is surrounded by several ‘normal’ two-atom molecules of hydrogen, also in green. The new chain configuration appears in the new material NaH7, which was produced under high pressure and high temperature conditions. The new material could change the superconductivity landscape and be useful for hydrogen storage in hydrogen fuel cells. Credit: Image courtesy Duck Young Kim

Scientists have looked for different ways to force hydrogen into a metallic state for decades. A metallic state of hydrogen is a holy grail for materials science because it could be used for superconductors...

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