Category Chemistry/Nanotechnology

Flipping a Chemical Switch helps Perovskite Solar Cells Beat the Heat

Thin films of crystalline materials called perovskites provide a promising new way of making inexpensive and efficient solar cells. Now, an international team of researchers has shown a way of flipping a chemical switch that converts one type of perovskite into another -- a type that has better thermal stability and is a better light absorber. Credit: Padture Lab / Brown University

Thin films of crystalline materials called perovskites provide a promising new way of making inexpensive and efficient solar cells. Now, an international team of researchers has shown a way of flipping a chemical switch that converts one type of perovskite into another — a type that has better thermal stability and is a better light absorber. Credit: Padture Lab / Brown University

Thin films of crystalline materials, perovskites provide a promising new way of making inexpensive and efficient solar cells. An international team has shown a way of flipping a chemical switch that converts one type of perovskite into another – a type that has better thermal stability and is a better light absorber...

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Successful test of Photoswitchable Anti-Tumor Agent

The GS-DProSw molecule in its inactive form (blue) can be activated by visible light (red) and “switched off” again by UV light. Credit: KIT

The GS-DProSw molecule in its inactive form (blue) can be activated by visible light (red) and “switched off” again by UV light. Credit: KIT

Photoswitchable agents might reduce side effects of chemotherapy. So far, photodynamic therapies have been dependent on oxygen in the tissue. But hardly any oxygen exists in malignant, rapidly growing tumors. A group of researchers of KIT and the University of Kiev has now developed a photo-switchable molecule as a basis of an oxygen-independent method.

Photodynamic therapy (PDT) in medicine usually uses a substance that reacts to light and converts the oxygen in the tissue into aggressive radicals. These reactive substances are toxic and damage the neighboring cells, such that e.g. tumors are decomposed...

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Making Biodiesel with Used Cooking Oil and a Microwave

SiO2 Beads Decorated with SrO Nanoparticles for Biodiesel Production from Waste Cooking Oil Using Microwave Irradiation.

SiO2 Beads Decorated with SrO Nanoparticles for Biodiesel Production from Waste Cooking Oil Using Microwave Irradiation.

Weaning cars and trucks off of gasoline and diesel made from fossil fuels is a difficult task. One promising solution involves biodiesel, which comes from natural oils and fats, but it is costly. Using a microwave and catalyst-coated beads, scientists have devised a new way to convert waste cooking oil into biodiesel that could make it more affordable. They report how they did it in ACS’ journal Energy & Fuels.

Biodiesel has many advantages over traditional fuels. It is renewable, biodegradable and emits less CO2. It can also easily take the place of conventional diesel without the need for carmakers to modify engines...

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Researchers develop new Semiconducting Polymer for forthcoming Flexible Electronics

While high-mobility p-type conjugated polymers have been widely reported, high-mobility n-type conjugated polymers are still rare. In the present work, we designed semifluorinated alkyl side chains and introduced them into naphthalene diimide-based polymers (PNDIF-T2 and PNDIF-TVT). We found that the strong self-organization of these side chains induced a high degree of order in the attached polymer backbones by forming a superstructure composed of “backbone crystals” and “side-chain crystals”. This phenomenon was shown to greatly enhance the ordering along the backbone direction, and the resulting polymers thus exhibited unipolar n-channel transport in field-effect transistors with remarkably high electron mobility values of up to 6.50 cm2 V–1 s–1 and with a high on–off current ratio of 105.

While high-mobility p-type conjugated polymers have been widely reported, high-mobility n-type conjugated polymers are still rare. In the present work, we designed semifluorinated alkyl side chains and introduced them into naphthalene diimide-based polymers (PNDIF-T2 and PNDIF-TVT). We found that the strong self-organization of these side chains induced a high degree of order in the attached polymer backbones by forming a superstructure composed of “backbone crystals” and “side-chain crystals”. This phenomenon was shown to greatly enhance the ordering along the backbone direction, and the resulting polymers thus exhibited unipolar n-channel transport in field-effect transistors with remarkably high electron mobility values of up to 6...

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