Category Chemistry/Nanotechnology

The Solar Thermal Electrochemical Process (STEP) converts atmospheric carbon dioxide into carbon nanotubes that can be used in advanced batteries. Credit: Julie Turner, Vanderbilt University

s can be replaced with carbon recovered from the atmosphere. The team adapted a solar-powered process that converts carbon dioxide into carbon so that it produces carbon nanotubes that can be incorporated into both lithium-ion batteries like those used in electric vehicles and electronic devices and low-cost sodium-ion batteries under development for large-scale applications, such as the electric grid.

“This approach not only produces better batteries but it also establishes a value for carbon dioxide recovered from the atmosphere that is associated with the end-user battery cost unlike most efforts to...

Photo of Nano-Bio System A schematic of the nano-biosystem (top) and an electron microscope image of quantum rods

A transformational advance has been made in an alternate lighting source, one that doesn’t require a battery or a plug: high-efficient energy transfer between semiconductor quantum rods and luciferase enzymes. Quantum rods and luciferase enzymes are nanomaterials and biomaterials, respectively. When combined correctly, these materials produce bioluminescence – except, instead of coming from a biomaterial, such as a firefly enzyme, the light eminates from a nanomaterial, and is green, orange, red, or near-infrared in color.

Each quantum rods is 4 nm wide and 50 nm long...

Step by step towards the complete shell: Formation of a metal cluster from the atomic constituents to the compound. Credit: Dehnen Group, Philipps-Universität Marburg

First the nucleus, then the shell: Researchers from Marburg and Karlsruhe have studied stepwise formation of metal clusters, smallest fractions of metals in molecular form. The shell gradually forms around the inner atom rather than by later inclusion of the central atom. Knowledge of all development steps may allow for customized optoelectronic and magnetic properties.

To specifically synthesize chemical compounds, mechanisms responsible for their formation have to be known. “Purely inorganic compounds are a black box in this respect,” Florian Weigend of KIT and Stefanie Dehnen of Philipps-Universität Marburg explain...

Polyhedral representation of the crystal structure of fluoride-phosphate of vanadium and potassium. The yellow denotes a three-dimensional channel system, which provides rapid transport of Li+ ions. Credit: Stanislav Fedotov

A cathode material for li-ion batteries with a very high charge rate – down to 90s – has been created, retaining more than 75% of an initial capacity. The discovery may stipulate the development of batteries where expensive lithium could be replaced with cheaper potassium.

Nowadays Li-ion batteries power a wide range of electronic devices: mobile phones, tablets, laptops. They became popular in 90s and subsequently ousted widespread nickel-metal hydride batteries. However, their capacity may drop when temperature falls below 0...