Category Chemistry/Nanotechnology

Making the Invisible Visible: Color-Changing Indicators Highlight Microscopic Damage

When cracks form, microbeads embedded in the material break open and cause a chemical reaction that highlights the damaged area. Credit: Image courtesy Nancy Sottos

When cracks form, microbeads embedded in the material break open and cause a chemical reaction that highlights the damaged area. Credit: Image courtesy Nancy Sottos

Damage developing in a material can be difficult to see until something breaks or fails. A new polymer damage indication system automatically highlights areas that are cracked, scratched or stressed, allowing engineers to address problem areas before they become more problematic. The early warning system would be particularly useful in applications like petroleum pipelines, air and space transport, and automobiles – applications where one part’s failure could have costly ramifications that are difficult to repair.

“Polymers are susceptible to damage in the form of small cracks that are often difficult to detect...

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New Lithium-ion Battery Shuts down at High Temperatures, Restarts when it Cools

Stanford researchers are using spiky nanoparticles of graphene-coated nickel to create a lithium-ion battery that shuts down when it's too hot, then quickly restarts when it cools (1µ =1 micrometer). Credit: Zheng Chen, Stanford University

Stanford researchers are using spiky nanoparticles of graphene-coated nickel to create a lithium-ion battery that shuts down when it’s too hot, then quickly restarts when it cools (1µ =1 micrometer). Credit: Zheng Chen, Stanford University

The new technology could prevent the kind of fires that have prompted recalls and bans on a wide range of battery-powered devices, from recliners and computers to navigation systems and hoverboards. “People have tried different strategies to solve the problem of accidental fires in lithium-ion batteries,” said Prof. Zhenan Bao, chemical engineering, Stanford. It “can be shut down and revived over repeated heating and cooling cycles without compromising performance.”

A typical Li-ion battery consists of 2 electrodes and a liquid or gel electrolyte that c...

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Researchers’ Metallic Glue may Stick it to Soldering and Welding

a) Coated rods are arranged along a sub­strate, like angled teeth on a comb. b) The teeth are then inter­laced. c) When indium and galium come into con­tact, they form a liquid. d) The metal core of the rods turns that liquid into a solid. The resulting glue pro­vides the strength and thermal/​electrical con­duc­tance of a metal bond. From “Advanced Mate­rials & Processes,” Jan­uary 2016

a) Coated rods are arranged along a sub­strate, like angled teeth on a comb. b) The teeth are then inter­laced. c) When indium and galium come into con­tact, they form a liquid. d) The metal core of the rods turns that liquid into a solid. The resulting glue pro­vides the strength and thermal/​electrical con­duc­tance of a metal bond. From “Advanced Mate­rials & Processes,” Jan­uary 2016

Experts in nanotechnology have developed a glue that binds metal to metal to glass to you-name-it, sets at room temp, and requires little pressure to seal. “MesoGlue was founded by Huang and two of his PhD stu­dents: They had a dream of a better way of sticking things together...

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Damaged Material, Heal Thyself

Secretion in droplet-embedded gel permits self-repairing behavior. Three-dimensional confocal fluorescence images show damaged gel (top) after 0.5 hours and the self-repaired gel after 72 hours (bottom). Credit: Image courtesy of Joanna Aizenberg

Secretion in droplet-embedded gel permits self-repairing behavior. Three-dimensional confocal fluorescence images show damaged gel (top) after 0.5 hours and the self-repaired gel after 72 hours (bottom). Credit: Image courtesy of Joanna Aizenberg

Inspired by healing wounds in skin, a new approach protects and heals surfaces using a fluid secretion process. In response to damage, dispersed liquid-storage droplets are controllably secreted. The stored liquid replenishes the surface and completes the repair of the polymer in seconds to hours.

The fluid secretion approach to repair the material has also been demonstrated in fibers and microbeads...

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