Category Chemistry/Nanotechnology

Solving one of the most intriguing Q’s in Astrochemistry: DIBs

This artist's conception symbolically represents complex organic molecules, known as polycyclic aromatic hydrocarbons, seen in the early universe. These large molecules, comprised of carbon and hydrogen, are among the building blocks of life. NASA's Spitzer Space Telescope is the first telescope to see polycyclic aromatic hydrocarbons so early--10 billion years further back in time than seen previously. Credit: NASA/JPL-Caltech/T. Pyle (SSC)

This artist’s conception symbolically represents complex organic molecules, known as polycyclic aromatic hydrocarbons, seen in the early universe. These large molecules, comprised of carbon and hydrogen, are among the building blocks of life. NASA’s Spitzer Space Telescope is the first telescope to see polycyclic aromatic hydrocarbons so early–10 billion years further back in time than seen previously. Credit: NASA/JPL-Caltech/T. Pyle (SSC)

DIBs  (diffuse interstellar bands) are a collection of about 400 absorption bands that show up in spectra of light that reaches the earth after traversing interstellar medium. Indications exist they may arise from the presence of large hydrocarbon molecules. Recent experiments lend novel credibility to this hypothesis.

Among the hydrocarbons that are p...

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Building Computers from DNA?

Graphical abstract: Reversible DNA i-motif to hairpin switching induced by copper(ii) cations

i-Motif DNA structures have previously been utilised for many different nanotechnological applications, but all have used changes in pH to fold the DNA. Herein we describe how copper(II) cations can alter the conformation of i-motif DNA into an alternative hairpin structure which is reversible by chelation with EDTA

Scientists can now ‘switch’ the structure of DNA using copper salts and EDTA. Ethylenediaminetetraacetic acid is an agent commonly found in shampoo and other household products. The applications for this discovery include nanotechnology – where DNA is used to make tiny machines, and in DNA-based computing – where computers are built from DNA rather than silicon...

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‘Diamonds from the sky’ approach turns CO2 into valuable Carbon Nanofibers

Researchers are generating carbon nanofibers (above) from CO2 , removing a greenhouse gas from the air to make products. Credit: Stuart Licht, Ph.D.

Researchers are generating carbon nanofibers (above) from CO2 , removing a greenhouse gas from the air to make products. Credit: Stuart Licht, Ph.D.

Finding a technology to shift carbon dioxide, the most abundant anthropogenic greenhouse gas, from a climate change problem to a valuable commodity has long been a dream. Now, a team of chemists have developed a technology to economically convert CO2 directly into carbon nanofibers for industrial and consumer products. “Such nanofibers are used to make strong carbon composites, such as those used in the Boeing Dreamliner, as well as in high-end sports equipment, wind turbine blades and a host of other products.”

Previously, the researchers had made fertilizer and cement without emitting CO2. Licht calls his approach “diamonds from the sky...

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Comet Impacts may have led to Life on Earth – and perhaps elsewhere

C/2006 P1 Comet McNaught, the 'Great Comet of 2007', as seen from Swift's Creek, Victoria, Australia on 23 January 2007. Image credit: Fir0002 / Flagstaffotos / Wikimedia Commons CC BY-SA 3.0.

C/2006 P1 Comet McNaught, the ‘Great Comet of 2007′, as seen from Swift’s Creek, Victoria, Australia on 23 January 2007. Image credit: Fir0002 / Flagstaffotos / Wikimedia Commons CC BY-SA 3.0.

Substantial synthesis of peptides – the first building blocks of life may have been driven by comet impacts. Dr Sugahara from JAMSTEC in Yokahama, and Dr Koichi Mimura, from Nagoya University performed a series of experiments to mimic the conditions of comet impacts on the Early Earth at the time when life first appeared, around 4 billion years ago.

They took frozen mixtures of amino acid, water ice and silicate (forsterite) at cryogenic condition (77 K), and used a propellant gun to simulate the shock of a comet impact...

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