Mechanics know molybdenum disulfide (MoS2) as a useful lubricant in aircraft and motorcycle engines and in the CV and universal joints of trucks and automobiles. Rice University researcher Isabell Thomann knows it as a remarkably light-absorbent substance that holds promise for the development of energy-efficient optoelectronic and photocatalytic devices.
“Basically, we want to understand how much light can be confined in an atomically thin semiconductor monolayer of MoS2,” said Assitant/Prof Thomann. “By using simple strategies, we were able to absorb 35 to 37% of the incident light in the 400- to 700-nm wavelength range, in a layer that is only 0.7nm thick.” The research has many applications, including development of efficient and inexpensive photovoltaic solar panels.
“Squeezing light into these extremely thin layers and extracting the generated charge carriers is an important problem in the field of two-dimensional materials,” she said. “That’s because monolayers of 2-D materials have different electronic and catalytic properties from their bulk or multilayer counterparts.”
Thomann and her team used a combination of numerical simulations, analytical models and experimental optical characterizations. Using three-dimensional electromagnetic simulations, they found that light absorption was enhanced 5.9 times compared with using MoS2 on a sapphire substrate.
“If light absorption in these materials was perfect, we’d be able to create all sorts of energy-efficient optoelectronic and photocatalytic devices. That’s the problem we’re trying to solve,” Thomann said. She is pleased with her lab’s progress but concedes that much work remains to be done. “The goal, of course, is 100% absorption, and we’re not there yet.” http://news.rice.edu/2016/05/04/molybdenum-disulfide-holds-promise-for-light-absorption/
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