Upsizing Nanostructures into Light, Flexible 3D Printed Metallic materials

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Researchers have developed hierarchical metallic metamaterial with multi-layered, fractal-like 3-D architectures to create structures at centimeter scales incorporating nanoscale features. Credit: Jim Stroup/Virginia Tech

Researchers have developed hierarchical metallic metamaterial with multi-layered, fractal-like 3-D architectures to create structures at centimeter scales incorporating nanoscale features. Credit: Jim Stroup/Virginia Tech

For years, materials have been made at the nanoscale level to take advantage of their mechanical, optical, and energy properties, but efforts to scale these materials to larger sizes have resulted in diminished performance and structural integrity. Now, researchers describe a new process to create lightweight, strong and super elastic 3D printed metallic nanostructured materials with unprecedented scalability, 7 orders of magnitude control of arbitrary 3D architectures.

Strikingly, these multiscale metallic materials have displayed super elasticity because of their designed hierarchical 3D architectural arrangement and nanoscale hollow tubes, resulting in more than a 400% increase of tensile elasticity over conventional lightweight metals and ceramic foams. The approach, which produces multiple levels of 3D hierarchical lattices with nanoscale features, could be useful anywhere there’s a need for a combination of stiffness, strength, low-weight, high flexibility – such as in structures to be deployed in space, flexible armors, lightweight vehicles and batteries, opening the door for applications in aerospace, military and automotive industries.

A new process allows materials synthesized at the nano-level to be scaled to larger sizes to take advantage of their mechanical, optical, and energy properties.

A new process allows materials synthesized at the nano-level to be scaled to larger sizes to take advantage of their mechanical, optical, and energy properties.

Natural materials, such as trabecular bone and the toes of geckoes, have evolved with multiple levels 3-D architectures spanning from the nanoscale to the macroscale. Human-made materials have yet to achieve this delicate control of structural features.Zheng said. “Assembling nanoscale features into billets of materials through multi-leveled 3D architectures, you begin to see a variety of programmed mechanical properties such as minimal weight, maximum strength and super elasticity at centimeter scales.”

The process Zheng and his collaborators use to create the material is an innovation in a digital light 3D printing technique that overcomes current tradeoffs between high resolution and build volume, a major limitation in scalability of current 3D printed microlattices and nanolattices. Related materials that can be produced at the nanoscale eg graphene sheets can be 100X stronger than steel, but trying to upsize these materials in 3 dimensions degrades their strength eight orders of magnitude, ie they become 100 million times less strong.

Zheng

Xiaoyu ‘Rayne’ Zheng

“The increased elasticity and flexibility obtained through the new process and design come without incorporating soft polymers, thereby making the metallic materials suitable as flexible sensors and electronics in harsh environments, where chemical and temperature resistance are required,” Zheng added.

These multi-leveled hierarchical lattice also means more surface area is available to collect photons energies as they can enter the structure from all directions and be collected not just on the surface, like traditional photovoltaic panels, but also inside the lattice structure. One of the great opportunities this study creates is the ability to produce multi-functional inorganic materials such as metals and ceramics to explore photonic and energy harvesting properties in these new materials
http://vtnews.vt.edu/articles/2016/07/me-upsizednanostructures.html