Category Chemistry/Nanotechnology

The Best Semiconductor of them all?

Ball-and-stick model of four molecules in a crystal, each with one gray atom surrounded by four red atoms
Caption:MIT researchers say cubic boron arsenide is the best semiconductor material ever found, and maybe the best possible one.
Credits:Image: Christine Daniloff, MIT

A material known as cubic boron arsenide has two major advantages over silicon, research shows. It provides high mobility to both electrons and holes, and it has excellent thermal conductivity. It is, the researchers say, the best semiconductor material ever found.

Silicon is one of the most abundant elements on Earth, and in its pure form the material has become the foundation of much of modern technology, from solar cells to computer chips. But silicon’s properties as a semiconductor are far from ideal.

For one thing, although silicon lets electrons whizz through its structure easily, it is much less accommodating...

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All-in-one Solar-powered Tower makes Carbon-Neutral Jet Fuel

•Entire process chain from H2O and CO2 to solar kerosene realized in a solar tower
•50-kW solar reactor demonstrated for ceria-based thermochemical redox splitting
•Consecutive redox cycling produced syngas suitable for FT synthesis
•4.1% solar-to-syngas energy efficiency achieved without implementing heat recovery

Researchers have designed a fuel production system that uses water, carbon dioxide (CO2), and sunlight to produce aviation fuel. They have implemented the system in the field, and the design, publishing July 20 in the journal Joule, could help the aviation industry become carbon neutral.

“We are the first to demonstrate the entire thermochemical process chain from water and CO2 to kerosene in a fully-integrated solar tower system,” says Aldo Steinfeld (@solarfuels), ...

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Future Smart Homes could be Powered with Electronics built on Stones

An array of stones
Interconnected microenergy devices built on marble tiles create customizable 3D power supply systems.
Credit: Adapted from ACS Nano 2022, DOI: 10.1021/acsnano.2c01753

What if you could power the smart thermostats, speakers and lights in your home with a kitchen countertop? Stones, such as marble and granite, are natural, eco-friendly materials that many people building or renovating houses already use. Now, in a step toward integrating energy storage with these materials, researchers have fabricated microsupercapacitors onto the surface of stone tiles. The devices, reported in ACS Nano, are durable and easily scaled up for customizable 3D power supplies.

It would be convenient if the surfaces in rooms could charge smart home devices or other small electronics without being connected ...

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A Ceramic Aerogel made with Nanocrystals and Embedded in a Matrix for use in Thermal Insulation Applications

A ceramic aerogel made with nanocrystals and embedded in a matrix for use in thermal insulation applications
Multiscale design of hypocrystalline ceramic nanofibrous aerogel. a, Deformation modes and the corresponding ν and α of crystalline (C), amorphous (A) and hypocrystalline (H) ceramic fibrous cells under mechanical and thermal excitations. The colored scale bar indicates the variation of ceramics from amorphous to crystal by using a local-entropy-based fingerprint to characterize the crystallinity of each atom in the simulated system. b, Illustration of the zig-zag architecture design based on hypocrystalline fibrous ceramics. The units of the colored scale bars are millimeters, presenting absolute displacement values in ν and α calculation. The triangle, square and pentagon cells are the building units to assemble the fibrous aerogel structure. Credit: Nature (2022). DOI: 10...
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